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Figure 2 presents the apparent morphologies of the aboriginal TFC and TFN membranes. The aboriginal polyamide band has a archetypal ridge-and-valley assay with about big “leaves”. Afterwards accumulation STCAss and SCA, the resultant polyamide layers still acquire ridge-and-valley morphologies but the “leaves” become smaller. In addition, the array of the polyamide band decreases with the accession of nano-fillers possibly due to the acerb attributes of STCAss and SCA, which acquire four sulfonate and sulfonic acerbic groups in one molecule, respectively. Amid them, TFN-SCA-1.5 has the thinnest careful layer. The pH ethics of the m-phenylenediamine (MPD) solutions affirm our hypothesis. The MPD solutions absolute 1.5 wt% STCAss and SCA accept pH ethics of ~6.6 and 5.5, respectively, while the aboriginal MPD band-aid has a pH bulk of ~9. Aback the sulfonate and sulfonic acerbic groups in STCAss and SCA may collaborate with MPD, their attendance interferes the interfacial polymerization process26. Moreover, the proton dissociated from the sulfonic acerbic groups would arrest the HCl bearing during the interfacial polymerization because it accouterment the acknowledgment calm backward. Both factors aftereffect in a lower bulk of cross-linking acknowledgment amid MPD and trimesoyl chloride (TMC) during the interfacial polymerization, arch to a beneath channelled polyamide layer.



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FESEM and AFM images of the polyamide layers for a TFC-0, b TFN-STCAss-1.5, and c TFN-SCA-1.5.



A allegory of the apparent assay amid TFN membranes anchored with STCAss and SCA indicates that TFN-STCAss-1.5 has abate “leaves” than TFN-SCA-1.5, although the closing has a hardly lower pH than the former. This may be acquired by the Na ions appear from STCAss. The interfacial polymerization acknowledgment about takes abode in two steps: (i) MPD in the aqueous actualization diffuses against the interface and reacts with TMC to anatomy a alpha polyamide band afterwards the ridge-and-valley structure; (ii) Marangoni alteration added prompts the clearing of MPD agilely to acknowledge with TMC, appropriately blame and angle the alpha polyamide band and basic a ridge-and-valley structure27,28. Aback Marangoni alteration is afflicted by the apparent astriction abreast the water/hexane interface and the accession of asleep electrolytes, such as Na and K , elevates the apparent astriction of water29, the attendance of Na from STCAss in the MPD band-aid may access the apparent astriction abreast the water/hexane interface, and abate the Marangoni convection, arch to a abate “leaves”.



The apparent cartography of these polyamide layers was added probed by diminutive force microscopy (AFM) to actuate the apparent roughness. As apparent in Fig. 2, the adjustment of apparent acerbity is constant with the ascertainment from acreage discharge scanning electron microscopy (FESEM) images, which follows TFC-0 > TFN-SCA-1.5 > TFN-STCAss-1.5. This adjustment added confirms the furnishings of pH and Na on the accumulation of polyamide band during the interfacial polymerization.

The apparent chemistries of the aboriginal and adapted polyamide layers were characterized by Fourier transform bittersweet spectroscopy (FTIR) beneath the attenuated absolute reflectance (ATR) approach and X-ray photoelectron spectroscopy (XPS) application free-standing polyamide films. Figure 3 displays the ATR-FTIR spectra of TFC-0, TFN-STCAss-1.5, and TFN-SCA-1.5. The aboriginal polyamide band consists of the archetypal N-H and C=O bonds of amide groups, which actualization aciculate accession peaks at 3300 cm−1 and 1620 cm−1, respectively. In comparison, afterwards STCAss and SCA incorporation, the aciculate N-H accession aiguille of the amide accumulation is covered by a ample O-H accession aiguille in the ambit of 3200–3650 cm−1, while an S=O accession aiguille at 1149 cm−1 appears. The O-H and S=O bonds accord to the hydroxyl and sulfonate/sulfonic acerbic groups of STCAss and SCA, respectively. This indicates the acknowledged assimilation of both STCAss and SCA into the polyamide layers. However, it is difficult to assay the aberration amid TFN-STCAss-1.5 and TFN-SCA-1.5 from the ATR-FTIR spectra because the C-S band shows a anemic aiguille in FTIR that is usually covered by added peaks. Therefore, XPS is active to added investigate the apparent agreement and bonding advice of the free-standing TFC and TFN membranes.

ATR-FTIR spectra for TFC-0, TFN-STCAss-1.5, and TFN-SCA-1.5.

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Supplementary Table 1 tabulates the apparent compositions of these polyamide layers. The S atom can hardly be detected in the aboriginal polyamide band although there is a tiny bulk of sodium dodecyl sulfate (SDS; 0.2 wt%) in the MPD aqueous solution. By accumulation STCAss and SCA, the S capacity in the polyamide layers access to 0.34 At% and 0.26 At%, respectively. The S agreeable of TFN-STCAss-1.5 is college than that of TFN-SCA-1.5 because anniversary STCAss atom consists of 8 S atoms and anniversary SCA atom possesses alone 4 S atoms. The C capacity are agnate for the three polyamide layers; however, the O capacity access while the N capacity abatement afterwards the assimilation of STCAss and SCA. This is due to the actuality that STCAss and SCA acquire aerial concentrations of O elements, attributable to both hydroxyl and sulfonate/sulfonic acerbic groups but no N elements.

To added assay the apparent chemistry, the N 1 s and S 2 p XPS spectra are deconvoluted and displayed in Fig. 4a. For the N peak, there are three adapted peaks; namely, (1) primary amine from the partially cross-linked MPD monomer, (2) accessory amine for the polyamide group, and (3) quaternary amine. The percentages of their aiguille areas are affected and listed in Supplementary Table 2. The allotment of the accessory amine decreases decidedly with the assimilation of STCAss and SCA, while the capacity of both primary and quaternary amines access slightly. The abatement in accessory amine and the access in primary amine added affirm the lower cross-linking degrees in these two adapted polyamide layers as empiric in FESEM. Moreover, the access in quaternary amine agreeable may be due to the accumulation of ionic bonding amid the sulfonate/sulfonic acerbic groups and unreacted amine/amide groups. As elucidated in Fig. 1a, b, the sulfonate and sulfonic acerbic groups in STCAss and SCA are able electron abandoning groups; meanwhile, the amine and amide groups tend to accord electrons to them so that ionic bonds are formed, as depicted in Fig. 4b. This ionic bonding not alone ensures able interactions amid the congenital nano-fillers and the polyamide network, but additionally facilitates the burning of STCAss and SCA nano-fillers central the polyamide layer. As a result, the scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDX) angel of S elements in TFN-STCAss-1.5 (Supplementary Fig. 1) shows an alike administration beyond the film surface, advertence a akin burning of STCAss in the polyamide network. The ionic bonding amid the polyamide arrangement and STCAss/SCA would accomplish the developed TFN membranes aloft to those accepted TFN membranes in agreement of adherence and accord because the closing tends to alone accept concrete interactions amid the polyamide band and nano-fillers.

a Deconvolution of N 1 s and S 2 p XPS spectra for TFC-0, TFN-STCAss-1.5, and TFN-SCA-1.5, and b illustrations on the interactions amid polyamide arrangement and STCAss/SCA.

For the S 2 p XPS results, there is no accessible aiguille for the aboriginal polyamide layer, which is constant with the apparent agreement analysis. In contrast, the polyamide layers anchored with STCAss and SCA actualization two abstracted peaks and one aciculate peak, respectively. The two peaks for TFN-STCAss-1.5 are attributed to C-SO3 (168.5 eV) and C-S-C (164 eV), aback there are two types of sulfur atoms in STCAss30. For TFN-SCA-1.5, aback SCA alone contains C-SO3, there is alone one aciculate aiguille empiric at 168.5 eV. Thus, by application XPS, TFN-STCAss-1.5, and TFN-SCA-1.5 can be artlessly acclaimed from their S 2 p spectra.

In adjustment to investigate the abyss contour of microstructures and the change of chargeless aggregate and array in polyamide layers, TFC-0, TFN-STCAss-1.5, and TFN-SCA-1.5 were advised by positron abolishment spectroscopy (PAS). As illustrated in Fig. 5, the S- and R- ambit are acclimated to characterize the changes of chargeless aggregate and micro-voids as a action of positron assimilation abyss (i.e., film thickness), respectively. The S-parameter represents the acuteness of chargeless volume, area a beyond S-parameter stands for added chargeless aggregate cavities and/or a college chargeless volume. Similarly, the R-parameter describes the pore admeasurement distribution, area a beyond R-parameter agency that the voids (in nm to µm sizes) become beyond and/or their quantities increase.

a, b S-parameters and c, d R-parameters of TFC-0, TFN-STCAss-1.5, and TFN-SCA-1.5. The dotted ambit in b announce the boilerplate ethics of S-parameters of polyamide networks for allegorical the view.

As apparent in Fig. 5a, b (enlarged one), the S-parameters of all membranes access acutely first, which is acquired by the aback circulation and drop of positroniums abreast the film surface31. Then, TFC-0 exhibits a altered trend from the added two. Its S-parameter fluctuates at a assertive bulk and again increases further. The antecedent aberration represents the close polyamide band and the after access indicates the alteration from the close polyamide band to the cross-linked polyimide substrate. As the chargeless aggregate acuteness central the film is not alluringly akin forth the film depth, the S-parameter commonly fluctuates about a assertive akin instead of a bland line. In contrast, the S-parameters of TFN-STCAss-1.5 and TFN-SCA-1.5 ability the best ethics aboriginal at ~1–1.2 KeV and again abatement at college adventure energy, analogous the S-parameter of the substrate in TFC-0 at ~2.5 KeV. Thus, the S-parameter agnate to the positron activity of 0.5–2.5 KeV represents the polyamide layer. To facilitate accessible comparison, eye-guiding ambit that represent the boilerplate ethics of S-parameters in the ambit of 0.5–2.5 KeV, accept been added as dotted ambit in Fig. 5b. The boilerplate ethics of S-parameters, agnate to the polyamide layers, chase the adjustment of TFC-0 < TFN-STCAss-1.5 ≈ TFN-SCA-1.5. In addition, there is hardly any overlap amid TFC-0 and TFN-STCAss-1.5/TFN-SCA-1.5 in the ambit of 0.5–2.5 KeV, so the changes in chargeless aggregate acuteness by accumulation STCAss and SCA are advised to be significant. This confirms that the assimilation of STCAss and SCA into the polyamide arrangement can decidedly access its chargeless aggregate intensity.

The R-parameters of all membranes present a agnate trend, as advised in Fig. 5c, d. The R-parameter decreases at the alpha and alcove the everyman value, followed by a desperate increase, which forms a “V-shape” curve. The antecedent abatement and consecutive access betoken the actuality of a attenuate dense-selective layer. Thus, the ambit amid the antecedent point and the basal of the “V-shape” can be interpreted as the dense-layer thickness, and the minimum bulk of the “V-shape” indicates the everyman acuteness of voids. Constant with the ascertainment from FESEM images, the dense-layer array follows a bottomward adjustment of TFC-0 > TFN-STCAss-1.5 > TFN-SCA-1.5. In addition, the aboriginal TFC film has the aboriginal acuteness of voids, while the added two TFN membranes acquire a agnate acuteness of voids. In summary, the aboriginal polyamide band has the everyman acuteness of chargeless aggregate and voids as able-bodied as the better thickness; the STCAss-incorporated polyamide band is hardly thinner and has a about beyond acuteness of chargeless aggregate and voids; while the SCA-modified polyamide band possesses agnate acuteness of chargeless aggregate and voids as the STCAss-incorporated polyamide layer, but has the thinnest polyamide band amid them.

The OSFO performances of TFC-0, TFN-STCAss-1.5, and TFN-SCA-1.5 were quantified beneath FO and pressure-retarded assimilation (PRO) modes, application authentic booze and 2 M LiCl in booze as augment and draw solutions, respectively. Figure 6a, b shows their booze alteration (Jw), about-face solute alteration (Js), as able-bodied as Js/Jw. The aboriginal TFC film has a about low booze alteration and a aerial about-face alkali alteration beneath FO and PRO modes, which are not adorable for an FO membrane. In contrast, the STCAss-incorporated film has a affecting access in booze alteration beneath both FO and PRO modes due to its thinner polyamide band and a beyond chargeless volume, as accurate by PAS. Surprisingly, TFN-SCA-1.5 has about the above booze alteration as TFC-0, although the aloft has a college chargeless aggregate and a thinner polyamide band than the latter, as appear by PAS. Meanwhile, the about-face solute alteration follows the adjustment of TFC-0 > TFN-STCAss-1.5 > TFN-SCA-1.5. In added words, the STCAss and SCA-incorporated membranes accept abundant lower about-face solute fluxes than the aboriginal one, which additionally does not chase the trend of their chargeless volumes empiric by PAS.

OSFO achievement for a FO approach and b PRO mode, as able-bodied as c carriage backdrop and d diffusivities of water, methanol, and booze in TFC-0, TFN-STCAss-1.5, and TFN-SCA-1.5.

These absorbing phenomena may appear from the actuality that the close-loop macrocyclic molecules, i.e., STCAss and SCA, not alone action as pore formers but additionally act as absolute diminutive sieves that alone acquiesce baby molecules (i.e., abate than their atrium sizes) to canyon through and adios or block the big ones. According to the diminutive structures of STCAss and SCA fatigued and optimized by Material Studio®, Fig. 1 reveals that the diameters of the lower cavities in STCAss and SCA are ~5.1 Å and 4.2 Å, respectively. Aback the active bore of an booze atom is ~4.4 Å (refs. 32,33), booze can calmly canyon through the baby aperture of STCAss but may not go through SCA. As a consequence, alike admitting TFN-SCA-1.5 has a college chargeless aggregate and a thinner polyamide, it exhibits a agnate booze alteration to the aboriginal TFC membrane. Similarly, the baby cavities of both STCAss and SCA may adios Li and Cl− ions in booze although their solvated diameters in booze are not known. Nevertheless, the hydrated diameters of Li and Cl− are 7.64 Å and 6.64 Å, respectively34, which are abundant beyond than the baby atrium sizes of STCAss and SCA. Hence, the STCAss- and SCA-incorporated membranes adios Li , Cl−, and LiCl, and actualization low about-face solute fluxes in OSFO tests.

In adjustment to affirm our hypothesis, the carriage backdrop of these membranes were advised by barometer their authentic booze permeances (A) and alkali rejections (Rs) beneath the blocked filtration mode. Figure 6c shows that TFN-STCAss-1.5 possesses the accomplished authentic booze permeance, while TFN-SCA-1.5 has the everyman authentic booze permeance. The bounce against LiCl, NaCl, and KCl follows the adjustment of TFN-SCA-1.5 > TFN-STCAss-1.5 > TFC-0, which reconfirms our antecedent that both baby cavities of STCAss and SCA can finer adios Li , Cl−, and LiCl. For all three membranes, the rejections chase the adjustment of LiCl > NaCl > KCl, due to the altered sizes of solvated ions in ethanol. In addition, the carriage backdrop of booze abstinent beneath the blocked filtration approach are constant with those beneath OSFO modes. TFN-STCAss-1.5 consistently has the accomplished booze alteration amid these membranes. Although TFC-0 has a hardly college authentic booze permeance than TFN-SCA-1.5 beneath the blocked filtration mode, their booze fluxes beneath OSFO modes are similar. This may be due to the actuality that TFC-0 has a college about-face solute flux. Thus, the active force beyond this film is bargain that after-effects in a lower booze alteration beneath OSFO tests35,36.

The bread-and-butter carriage apparatus for the developed membranes was additionally advised by barometer authentic bread-and-butter permeances of water, methanol, ethanol, and again artful their diffusivities in the membranes according to the solution–diffusion model. As apparent in Fig. 6d, the bread-and-butter diffusivities of all membranes abatement as the bread-and-butter molecules become larger. This is in accordance to the diffusivity correlating equations, i.e., diffusivity is inversely accompanying to diminutive size. However, the trend of TFN-SCA-1.5 is hardly altered from those of TFC-0 and TFN-STCAss-1.5. The aloft has a abundant lower booze diffusivity than the closing because it has a stronger size-sieving aftereffect to block ethanol, as explained previously.

The tunable molecular-sieving backdrop of the bogus nanocomposites were additionally empiric in aqueous solutions, aback ethylene glycol (EG), diethylene glycol (DEG), and glucose were called as acid solutes for aqueous filtration tests (Supplementary Fig. 2). Interestingly, the bounce of TFN-SCA-1.5 against EG is abundant beyond than those of TFC-0 and TFN-STCAss-1.5. However, the rejections of both TFN-SCA-1.5 and TFN-STCAss-1.5 against DEG are agnate and are alone hardly college than that of TFC-0. Aback the bore of EG is 4.7 Å (ref. 37), it may alone be afar by SCA but not by STCAss. However, the bore of DEG is 5.82 Å, which could be alone by both SCA and STCAss. Meanwhile, a agnate trend in rejections can additionally be empiric for glucose, which is attributed to its bore of >7 Å. This abnormality added implies that both STCAss and SCA can molecularly tune the molecular-sieving backdrop of the bogus TFNs not alone in booze but additionally in aqueous solutions.

Based on the aloft results, STCAss is called as the acceptable nano-filler for added studies because it can access chargeless aggregate of the polyamide layer, abate its thickness, and advance aerial solute rejection. Thus, the STCAss loading in the MPD band-aid was assorted from 0 to 2.0 wt%, in adjustment to investigate the optimal loading and access the best OSFO performance. Supplementary Tables 3 and 4, and Fig. 3 abridge AFM, XPS, and FESEM results, respectively. Generally, an access in STCAss loading in the MPD band-aid after-effects in the polyamide apparent with a college S agreeable and a smoother polyamide band due to the above acerb effect. The bland polyamide band may be adorable to abbreviate abuse and advance a acceptable booze flux38.

Figure 7 illustrates the OSFO achievement beneath FO and PRO modes as a action of STCAss loading. In both modes, the booze alteration rapidly increases while the about-face solute alteration decidedly decreases, with an access in STCAss loading from 0 wt% to 1.5 wt%, arch to a adorable Js/Jw value. The aerial booze alteration guarantees a aerial booze accretion while the low about-face solute alteration helps in advancement the active force beyond the film and ensuring a abiding booze flux. In addition, the low Js/Jw bulk indicates a low arising of the draw solute to the augment beck and minimizes the abeyant hazard acquired by the about-face alteration of draw solutes. However, the booze alteration drops and the about-face solute alteration bounces aback significantly, aback an balance bulk of STCAss (2 wt%) is anchored in the polyamide layer. This is due to birthmark accumulation as apparent by the access in apparent acerbity and the actualization of bulges (Supplementary Table 3, Fig. 3). The TFN formed by accumulation 1.5 wt% STCAss in the MPD band-aid after-effects in the best OSFO performance. Comparing to the aboriginal TFC membrane, its booze fluxes are about angled beneath both FO and PRO mode. Interestingly, the allotment of accession beneath the FO approach (93.7%) is hardly lower than that of the PRO approach (112.2%) because of the ICP effect39. The aloft has a lower Js/Jw bulk of 0.07 than the closing of 0.12 application 2 M LiCl as the draw solution, respectively.

Ethanol alteration (closed square), about-face solute alteration (open circle), and Js/Jw (closed triangle) with accretion STCAss loading for a FO approach and b PRO mode. The augment band-aid is authentic booze and the draw band-aid is 2 M LiCl in ethanol.

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